Impact of RE/Ba change on RE2O3 phase and BaZrO3 nanorods at low temperature in REBCO superconducting film ZIWEI ZHOU, YANRU HUANG, GUOJUN CAI, RAJA DEVESH KUMAR MISRA vol. 62 (2024), no. 6, pp. 355 - 362 DOI: 10.31577/km.2024.6.355
Abstract The critical current density (Jc) dependence on an applied magnetic field was studied for a prototype REBCO with Zr doping content coated conductor fabricated by metal-organic chemical vapor deposition (MOCVD). The study revealed that different rare-earth (RE) cations were incorporated into the superconducting film to form RE2O3 and BaZrO3 (BZO). RE2O3 nanoparticles had a stronger pinning effect on magnetic flow along the direction of the a-b plane of films. With the increase of RE content, many RE2O3 nanoparticles effectively inhibited the precipitation of Ba-Cu-O heterophase, and when RE/Ba ≥ 0.65, the increase of coarse Ba-Cu-O phases wrecked the continuity of matrix and crystal quality of films, causing a decrease on Jc (90°). After excessive RE elements (RE/Ba = 0.70) were doped in film, RE2O3 phases were changed from granular to lamellar and cut off the continuous growth of BZO along the c-axis, reducing Jc (0°) of films. Key words rare-earth barium copper oxide (REBCO), RE2O3, BZO, rare-earth (RE), critical current density (Jc) Full text (1073 KB)
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