Structure and properties of melt-spun Al-Zr-Ti alloys. III. Phase transformations at elevated temperatures MALEK, P., CHALUPA, B., PLESTIL, J. vol. 38 (2000), no. 2, pp. 77 - 95
Abstract Rapidly solidified Al-Zr-Ti alloys are far from thermodynamic equilibrium. Electrical resistance measurements revealed two stages of microstructure changes occurring at elevated temperatures. Using the results of X-ray diffraction analysis the first stage was explained by the precipitation of the metastable Al3(ZrxTi1-x) phase with L12 structure and the second stage by the formation of the stable Al3(ZrxTi1-x) phase with DO23 or DO22 structure. Ti atoms substitute for Zr atoms in the lattices of these phases. This substitution improves the lattice mismatch between the particles of the Al3(ZrxTi1-x) phase and the matrix and shifts the individual decomposition stages to higher temperatures. Consequently, a better structure and strength stability may be expected. Key words Al-based alloys for elevated temperatures, rapid solidification, phase transformations, electrical resistance, X-ray analysis Full text (6248 KB)
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